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Liquid Phase Hydrogenation of Maleic Acid Diethyl Ester and Its Mixture with 4-Nitrotoluene over Modified Skeletal Nickel

Received: 17 February 2017     Accepted: 10 March 2017     Published: 28 November 2017
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Abstract

4-aminotoluene is known as a good octane additive, the mixture of maleic acid diethyl ester and Succinate acid diethyl ester has good lubricating characteristics. The process of hydrogenation of maleic acid diethyl ester at atmospheric pressure in aqueous solution of 2-propanol over skeletal nickel and modified skeletal one was investigated. It is established that the nickel surface modification by sulfur does not lead to the increase of the catalyst activity in the hydrogenation of maleic acid diethyl ester as opposed to 4-nitrotoluene. The principal possibility of selective hydrogenation of mixture of maleic acid diethyl ester with 4-nitrotoluene was demonstrated.

Published in International Journal of Oil, Gas and Coal Engineering (Volume 5, Issue 6)
DOI 10.11648/j.ogce.20170506.15
Page(s) 153-157
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Liquid-Phase Hydrogenation, 4-Nitrotoluene, Maleic Acid Diethyl Ester, Skeletal Nickel

References
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Cite This Article
  • APA Style

    Andrei Vladimirovich Afineevskii, Tatiana Yurievna Osadchaia, Dmitrii Alekseevich Prozorov, Mikhail Viktorovich Lukin, Yaroslav Pavlovich Suhachev, et al. (2017). Liquid Phase Hydrogenation of Maleic Acid Diethyl Ester and Its Mixture with 4-Nitrotoluene over Modified Skeletal Nickel. International Journal of Oil, Gas and Coal Engineering, 5(6), 153-157. https://doi.org/10.11648/j.ogce.20170506.15

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    ACS Style

    Andrei Vladimirovich Afineevskii; Tatiana Yurievna Osadchaia; Dmitrii Alekseevich Prozorov; Mikhail Viktorovich Lukin; Yaroslav Pavlovich Suhachev, et al. Liquid Phase Hydrogenation of Maleic Acid Diethyl Ester and Its Mixture with 4-Nitrotoluene over Modified Skeletal Nickel. Int. J. Oil Gas Coal Eng. 2017, 5(6), 153-157. doi: 10.11648/j.ogce.20170506.15

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    AMA Style

    Andrei Vladimirovich Afineevskii, Tatiana Yurievna Osadchaia, Dmitrii Alekseevich Prozorov, Mikhail Viktorovich Lukin, Yaroslav Pavlovich Suhachev, et al. Liquid Phase Hydrogenation of Maleic Acid Diethyl Ester and Its Mixture with 4-Nitrotoluene over Modified Skeletal Nickel. Int J Oil Gas Coal Eng. 2017;5(6):153-157. doi: 10.11648/j.ogce.20170506.15

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  • @article{10.11648/j.ogce.20170506.15,
      author = {Andrei Vladimirovich Afineevskii and Tatiana Yurievna Osadchaia and Dmitrii Alekseevich Prozorov and Mikhail Viktorovich Lukin and Yaroslav Pavlovich Suhachev and Marina Dmitrievna Chelysheva and Vladislav Olegovich Gundorov},
      title = {Liquid Phase Hydrogenation of Maleic Acid Diethyl Ester and Its Mixture with 4-Nitrotoluene over Modified Skeletal Nickel},
      journal = {International Journal of Oil, Gas and Coal Engineering},
      volume = {5},
      number = {6},
      pages = {153-157},
      doi = {10.11648/j.ogce.20170506.15},
      url = {https://doi.org/10.11648/j.ogce.20170506.15},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ogce.20170506.15},
      abstract = {4-aminotoluene is known as a good octane additive, the mixture of maleic acid diethyl ester and Succinate acid diethyl ester has good lubricating characteristics. The process of hydrogenation of maleic acid diethyl ester at atmospheric pressure in aqueous solution of 2-propanol over skeletal nickel and modified skeletal one was investigated. It is established that the nickel surface modification by sulfur does not lead to the increase of the catalyst activity in the hydrogenation of maleic acid diethyl ester as opposed to 4-nitrotoluene. The principal possibility of selective hydrogenation of mixture of maleic acid diethyl ester with 4-nitrotoluene was demonstrated.},
     year = {2017}
    }
    

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  • TY  - JOUR
    T1  - Liquid Phase Hydrogenation of Maleic Acid Diethyl Ester and Its Mixture with 4-Nitrotoluene over Modified Skeletal Nickel
    AU  - Andrei Vladimirovich Afineevskii
    AU  - Tatiana Yurievna Osadchaia
    AU  - Dmitrii Alekseevich Prozorov
    AU  - Mikhail Viktorovich Lukin
    AU  - Yaroslav Pavlovich Suhachev
    AU  - Marina Dmitrievna Chelysheva
    AU  - Vladislav Olegovich Gundorov
    Y1  - 2017/11/28
    PY  - 2017
    N1  - https://doi.org/10.11648/j.ogce.20170506.15
    DO  - 10.11648/j.ogce.20170506.15
    T2  - International Journal of Oil, Gas and Coal Engineering
    JF  - International Journal of Oil, Gas and Coal Engineering
    JO  - International Journal of Oil, Gas and Coal Engineering
    SP  - 153
    EP  - 157
    PB  - Science Publishing Group
    SN  - 2376-7677
    UR  - https://doi.org/10.11648/j.ogce.20170506.15
    AB  - 4-aminotoluene is known as a good octane additive, the mixture of maleic acid diethyl ester and Succinate acid diethyl ester has good lubricating characteristics. The process of hydrogenation of maleic acid diethyl ester at atmospheric pressure in aqueous solution of 2-propanol over skeletal nickel and modified skeletal one was investigated. It is established that the nickel surface modification by sulfur does not lead to the increase of the catalyst activity in the hydrogenation of maleic acid diethyl ester as opposed to 4-nitrotoluene. The principal possibility of selective hydrogenation of mixture of maleic acid diethyl ester with 4-nitrotoluene was demonstrated.
    VL  - 5
    IS  - 6
    ER  - 

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Author Information
  • Department of Physical and Colloidal Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo Region, Ivanovo, Russia

  • Department of Physical and Colloidal Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo Region, Ivanovo, Russia

  • Department of Physical and Colloidal Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo Region, Ivanovo, Russia

  • Department of Physical and Colloidal Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo Region, Ivanovo, Russia

  • Department of Physical and Colloidal Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo Region, Ivanovo, Russia

  • Department of Physical and Colloidal Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo Region, Ivanovo, Russia

  • Department of Physical and Colloidal Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo Region, Ivanovo, Russia

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